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The standard enthalpy change of neutralisation is the change in enthalpy that occurs when an acid and base undergo a neutralisation reaction to form one mole of water under standard conditions (298 K and 1 atm), i.e. react to produce water and a salt. It is a special case of the standard enthalpy change of reaction.

Equations for working out standard enthalpy of neutralisation:

 q=cm∆t 

Where q is the heat energy liberated in KJ . m is the mass or volume of the solution, usually volume of water in Kg. c is the specific thermal capacity of water normally 4.18. ∆T is the temperature change of the reaction between an acid and a base.

From this the standard enthalpy change (∆h) can be calculated by dividing the negative of q by the moles of the limiting reactant, usually moles of H+ ions.

Standard enthalpy change of neutralization=-57.3 kJ/mol

∆h=-q/n in kJmol-1

 the standard enthalpy of mineral acids is far greater than that of organic acids. this is because strong acids ionise completely and yet organic acids ionise partially. 


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