Petrochemicals are chemical products made from raw materials of petroleum or other hydrocarbon origin.[1] Although some of the chemical compounds that originate from petroleum may also be derived from other sources (such as coal or natural gas), petroleum is a major source of many.
This article is mainly intended to discuss organic compounds or materials that are not burned as fuel (see also Petroleum product).
The two main classes of petrochemical raw materials are olefins (including ethylene and propylene) and aromatics (including benzene and xylene isomers), both of which are produced in very large quantities. At oil refineries, olefins are produced mainly from hydrocarbons by processes such as fluid catalytic cracking and steam cracking. At oil refineries, aromatic hydrocarbons are mainly produced by catalytic reforming or similar processes. From these basic building blocks is made a very wide range of chemicals and other materials used in industry - monomers, solvents, detergents, and adhesives. From the monomers, polymers or oligomers are produced for plastics, resins, fibers, elastomers, certain lubricants, and gels.
World production of ethylene is around 110 million tonnes per annum, of propylene 65 million tonnes, and of aromatic raw materials 70 million tonnes. The largest petrochemical industries are to be found in the USA and Western Europe, though the major growth in new production capacity is in the Middle East and Asia. There is a substantial inter-regional trade in petrochemicals of all kinds.
Primary petrochemicals are divided into three groups depending on their chemical structure:[1]
[edit] List of significant petrochemicals and their derivatives
The following is a partial list of the major commercial petrochemicals and their derivatives:
- ethylene - the simplest olefin; used as a ripening hormone, a monomer and a chemical feedstock
- propylene - used as a monomer and a chemical feedstock
- C4 hydrocarbons - a mixture consisting of butanes, butylenes and butadienes
- isomers of butylene - useful as monomers or co-monomers
- 1,3-butadiene - a diene often used as a monomer or co-monomer for polymerization to elastomers such as polybutadiene or a plastic such as acrylonitrile-butadiene-styrene (ABS)
- synthetic rubbers - synthetic elastomers made of any one or more of several petrochemical (usually) monomers such as 1,3-butadiene, styrene, isobutylene, isoprene, chloroprene; elastomeric polymers are often made with a high percentage of conjugated diene monomers such as 1,3-butadiene, isoprene, or chloroprene
- higher olefins
- polyolefins such poly-alpha-olefins which are used as lubricants
- alpha-olefins - used as monomers, co-monomers, and other chemical precursors. For example, a small amount of 1-hexene can be copolymerized with ethylene into a more flexible form of polyethylene.
- other higher olefins
- detergent alcohols
- benzene - the simplest aromatic hydrocarbon
- ethylbenzene - made from benzene and ethylene
- styrene made by dehydrogenation of ethylbenzene; used as a monomer
- cumene - isopropylbenzene; a feedstock in the cumene process
- phenol - hydroxybenzene; of dassdcten made by the cumene process
- acetone - dimethyl ketone; also often made by the cumene process
- bisphenol A - a type of "double" phenol used in polymerization in epoxy resins and making a common type of polycarbonate
- solvents - liquids used for dissolving materials; examples often made from petrochemicals include ethanol, isopropyl alcohol, acetone, benzene, toluene, xylenes
- cyclohexane - a 6-carbon aliphatic cyclic hydrocarbon sometimes used as a non-polar solvent
- adipic acid - a 6-carbon dicarboxylic acid which can be a precursor used as a co-monomer together with a diamine to form an alternating copolymer form of nylon.
- nylons - types of polyamides, some are alternating copolymers formed from copolymerizing dicarboxylic acid or derivatives with diamines
- caprolactam - a 6-carbon cyclic amide
- nitrobenzene - can be made by single nitration of benzene
- alkylbenzene - a general type of aromatic hydrocarbon which can be used as a presursor for a sulfonate surfactant (detergent)
- chlorobenzene
- toluene - methylbenzene; can be a solvent or precursor for other chemicals
- mixed xylenes - any of three dimethylbenzene isomers, could be a solvent but more often precursor chemicals
- ortho-xylene - both methyl groups can be oxidized to form (ortho-)phthalic acid
- para-xylene - both methyl groups can be oxidized to form terephthalic acid
[edit] Petrochemicals products
[edit] See also
[edit] References
[edit] External links
