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Organoruthenium chemistry in chemistry is the study of organometallic compounds containing a carbon to ruthenium chemical bond [1]. The interest is mostly academic although several organoruthenium catalysts are of commercial interest. The chemistry has many similarities with organoiron chemistry with iron one element up in group 8 of the periodic table. The most important reagents for the introduction of ruthenium are ruthenium(III) chloride and triruthenium dodecacarbonyl. The related compound Ru(CO)5 is less attractive for this purpose because it decomposes:

Ru3(CO)12 + 3 CO \overrightarrow{\leftarrow} 3 Ru(CO)5

Compared to organopalladium chemistry ruthenium has fewer applications partially due to the higher coordination number and the wider variety in oxidation state (-2 to +6).

[edit] Ligands

The most important ligands for ruthenium are:

Norbornadiene dimerization

[edit] See also

  • Chemical bonds of carbon with other elements in the periodic table:
CH He
CLi CBe CB CC CN CO CF Ne
CNa CMg CAl CSi CP CS CCl Ar
CK CCa CSc CTi CV CCr CMn CFe CCo CNi CCu CZn CGa CGe CAs CSe CBr CKr
CRb CSr CY CZr CNb CMo CTc CRu CRh CPd CAg CCd CIn CSn CSb CTe CI CXe
CCs CBa CHf CTa CW CRe COs CIr CPt CAu CHg CTl CPb CBi CPo CAt Rn
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Uub Uut Uuq Uup Uuh Uus Uuo
↓
La CCe Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Ac Th Pa CU Np Pu Am Cm Bk Cf Es Fm Md No Lr


Chemical bonds to carbon
Core organic chemistry Many uses in chemistry.
Academic research, but no widespread use Bond unknown / not assessed.

[edit] References

  1. ^ Synthesis of Organometallic Compounds: A Practical Guide Sanshiro Komiya Ed. S. Komiya, M. Hurano 1997
  2. ^ Example: Organic Syntheses, Coll. Vol. 10, p.276 (2004); Vol. 77, p.1 (2000). Link
  3. ^ Example: Organic Syntheses, Organic Syntheses, Coll. Vol. 9, p.589 (1998); Vol. 71, p.1 (1993). Link
  4. ^ Example: Organic Syntheses, Organic Syntheses, Coll. Vol. 9, p.169 (1998); Vol. 72, p.74 (1995). Link
  5. ^ Example: Organic Syntheses, Vol. 81, p.178 (2005). Link
  6. ^ Another cumene Ru catalysis: Organic Syntheses, Organic Syntheses, Vol. 82, p.10 (2005).Link
  7. ^ Example: Organic Syntheses, Organic Syntheses, Vol. 82, p.188 (2005). Link



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