Lunar Ferroan Anorthosite #60025 (Plagioclase Feldspar). Collected by Apollo 16 from the Lunar Highlands near Descartes Crater. This sample is currently on display at the National Museum of Natural History in Washington, DC.

Moon rock describes rock that formed on the Moon (Earth's moon). The term is also loosely applied to other lunar materials collected during the course of human exploration of the Moon.

lunar sample collection case on display at the National Air and Space Museum

The rocks collected from the Moon are measured by radiometric dating techniques. They range in age from about 3.16 billion years old for the basaltic samples derived from the lunar maria, up to about 4.5 billion years old for rocks derived from the highlands.^[1] Based on the age dating technique of "crater counting," the youngest basaltic eruptions are believed to have occurred about 1.2 billion years ago,^[2] but we do not possess samples of these lavas. In contrast, the oldest ages of rocks from the Earth are between 3.8 and 4.28 billion years old.

There are currently three sources of Moon rocks on Earth: 1) those collected by US Apollo missions; 2) samples returned by the Soviet Union Luna missions; and 3) rocks that were ejected naturally from the lunar surface by cratering events and subsequently fell to Earth as lunar meteorites. During the six Apollo surface excursions, 2,415 samples weighing 382 kg (842 lb) were collected, the majority by Apollo 15, 16, and 17. The three Luna spacecraft returned with an additional 326 g (0.66 lb) of samples. Since 1980, over 120 lunar meteorites representing about 60 different meteorite fall events (none witnessed) have been collected on Earth, with a total mass of over 48 kg. About 1/3 of these were discovered by American and Japanese teams searching for Antarctic meteorites (e.g., ANSMET), with most of the remainder having been discovered by anonymous collectors in the desert regions of northern Africa and Oman.

Almost all lunar rocks are depleted in volatiles (such as potassium or sodium) and are completely lacking in the minerals found in Earth's water. In some regards, lunar rocks are closely related to Earth's rocks in their composition of the element oxygen. The Apollo moon rocks were collected using a variety of tools, including hammers, rakes, scoops, tongs, and core tubes. Most were photographed prior to collection to record the condition in which they were found. They were placed inside sample bags and then a Special Environmental Sample Container for return to the Earth to protect them from contamination. In contrast to the Earth, large portions of the lunar crust appear to be composed of rocks with high concentrations of the mineral anorthite. The mare basalts have relatively high iron values. Furthermore, some of the mare basalts have very high levels of titanium (in the form of ilmenite). A new mineral found on the Moon was armalcolite, named for the three astronauts on the Apollo 11 mission: Armstrong, Aldrin, and Collins.

[edit] Curation and availability

Genesis Rock returned by the Apollo 15 mission.

Samples in Lunar Sample Building at JSC

The main repository for the Apollo moon rocks is the Lunar Sample Building at the Lyndon B. Johnson Space Center in Houston, Texas. For safe keeping, there is also a smaller collection stored at Brooks Air Force Base in San Antonio, Texas. Most of the rocks are stored in nitrogen to keep them free of moisture. They are only handled indirectly, using special tools.

Moon rocks collected during the course of lunar exploration are currently considered priceless. In 1993, three small fragments from Luna 16, weighing 0.2g, were sold for US$ 442,500. In 2002, a safe, containing minute samples of lunar and martian material, was stolen from the Lunar Sample Building. The samples were recovered; in 2003, during the court case, NASA estimated the value of these samples at about $1 million for 285g (10 oz.) of material. Moon rocks in the form of lunar meteorites, although expensive, are widely sold and traded among private collectors.

Approximately two hundred small samples were mounted and presented to national governments and U.S. governors. At least one of these was later stolen, sold, and recovered.^[3] Other samples went to selected museums, including the National Air and Space Museum, the Kansas Cosmosphere and Space Center, the Ontario Science Centre, and to the visitor center at Kennedy Space Center where it is possible to "touch a piece of the moon," which is in fact a small moon rock cemented in a pillar in the center of a bank vault that is toured by visitors. The Tribune Tower in Chicago has a small piece in a display case facing Michigan Ave. NASA says that almost 295 kg (650 lb) of the original 382 kg (842 lb) of samples are still in pristine condition in the vault at Johnson Space Center.

NASA has made a number of educational packs comprising a disc of six small rock and soil samples in a lucite disc and a pack of thin petrological sections. They are available for exhibition and educational purposes in many countries, including Great Britain, where the samples are kept by the Science and Technology Facilities Council.

[edit] Classification

Moon rocks fall into two main categories, the ones found in the lunar highlands (terrae) or the maria. The terrae consist dominantly of mafic plutonic rocks. Regolith breccias with similar protoliths are also common. Mare basalts come in three distinct series in direct relation to their chemistry: high-Ti basalts, low-Ti basalts, and Very Low-Ti (VLT) basalts.

[edit] Highlands lithologies

Processing facility in Lunar Sample Building at JSC

Slice of moon rock at the National Air and Space Museum in Washington, DC

Primary igneous rocks in the lunar highlands compose three distinct groups: the ferroan anorthosite suite, the magnesian suite, and the alkali suite.

Lunar breccias, formed largely by the immense basin-forming impacts, are dominantly composed of highland lithologies because most mare basalts post-date basin formation (and largely fill these impact basins).

The ferroan anorthosite suite consists almost exclusively of the rock anorthosite (>90% calcic plagioclase) with less common anorthositic gabbro (70-80% calcic plagioclase, with minor pyroxene). The ferroan anorthosite suite is the most common group in the highlands, and is inferred to represent plagioclase flotation cumulates of the lunar magma ocean, with interstitial mafic phases formed from trapped interstitial melt or rafted upwards with the more abundant plagioclase framework. The plagioclase is extremely calcic by terrestrial standards, with molar anorthite contents of 94-96% (An94-96). This reflects the extreme depletion of the bulk moon in alkalis (Na, K) as well as water and other volatile elements. In contrast, the mafic minerals in this suite have low Mg/Fe ratios that are inconsistent with calcic plagioclase compositions. Ferroan anorthosites have been dated using the internal isochron method at "circa" 4.4 Ga.

The magnesian suite (or "mg suite") consists of dunites (>90% olivine), troctolites (olivine-plagioclase), and gabbros (plagioclase-pyroxene) with relatively high Mg/Fe ratios in the mafic minerals and a range of plagioclase compositions that are still generally calcic (An86-93). These rocks represent later intrusions into the highlands crust (ferroan anorthosite) at round 4.3-4.1 Ga. An interesting aspect of this suite is that analysis of the trace element content of plagioclase and pyroxene require equilibrium with a KREEP-rich magma, despite the refractory major element contents.

The alkali suite is so-called because of its high alkali content -- for moon rocks. The alkali suite consists of alkali anorthosites with relatively sodic plagioclase (An70-85), norites (plagioclasse-orthopyroxene), and gabbronorites (plagioclase-clinopyroxene-orthopyroxene) with similar plagioclase compositions and mafic minerals more iron-rich than the magnesian suite. The trace element contents of these minerals also indicates a KREEP-rich parent magma. The alkali suite spans an age range similar to the magnesian suite. Lunar granites are relatively rare rocks that include diorites, monzodiorites, and granophyres. They consist of quartz, plagioclase, orthoclase or alkali feldspar, rare mafics (pyroxene), and rare zircon. The alkali feldspar may have unusual compositions unlike any terrestrial feldspar, and they are often Ba-rich. These rocks apparently form by the extreme fractional crystallization of magnesian suite or alkali suite magmas, although liquid immiscibility may also play a role. U-Pb date of zircons from these rocks and from lunar soils have ages of 4.1-4.4 Ga, more or less the same as the magnesian suite and alkali suite rocks. In the 1960s, NASA researcher John A. O'Keefe and others linked lunar granites with tektites found on Earth although many researchers refuted these claims. According to one study, a portion of lunar sample 12013 has a chemistry that closely resembles javanite tektites found on Earth.

Lunar breccias range from glassy vitrophyre melt rocks, to glass-rich breccia, to regolith breccias. The vitrophyres are dominantly glassy rocks that represent impact melt sheets that fill large impact structures. They contain few clasts of the target lithology, which is largely melted by the impact. Glassy breccias form from impact melt that exit the crater and entrain large volumes of crushed (but not melted) ejecta. It may contain abundant clasts that reflect the range of lithologies in the target region, sitting in a matrix of mineral fragments plus glass that welds it all together. Some of the clasts in these breccias are pieces of older breccias, documenting a repeated history of impact brecciation, cooling, and impact. Regolith breccias resemble the glassy breccias but have little or no glass (melt) to weld them together. As noted above, the basin-forming impacts responsible for these breccias pre-date almost all mare basalt volcanism, so clasts of mare basalt are very rare. When found, these clasts represent the earliest phase of mare basalt volcanism preserved.

[edit] Mare basalts

Mare basalts are named for their frequent rate of constituting a large portion of the lunar maria. The lunar maria are made of mare basalts, which are like terrestrial basalts but have many important differences. The basalts show a large negative europium anomaly. Extraordinary potassium content can be found in a specific basalt, the so-called VHK (Very High K) basalt.

[edit] Thefts

[edit] Honduras Goodwill Moon Rock

In 1998 a unique Federal law enforcement undercover operation was created to identify and arrest individuals selling bogus moon rocks. This sting operation was known as Operation Lunar Eclipse. Originally two undercover agents were involved in this sting, Senior Special Agent Joseph Gutheinz of NASA's Office of Inspector General, posing as Tony Coriasso, and Inspector Bob Cregger of the United States Postal Inspection Service, posing as John Marta. This sting operation was later expanded to include Agents from the United States Customs Service. Agents posted an advertisement in USA Today asking for moon rocks. Agents were targeting individuals selling bogus moon rocks, but what they received was a solicitation to buy what turned out to be a gift President Richard Nixon gave to the people of Honduras in 1973, the Honduras Goodwill Moon Rock, one of 135 Apollo 17 moon rocks given to the nations of the world. The seller of this moon rock offered it to the undercover Agents for 5 million dollars, a huge amount for something that weighed only 1.142 grams.

After two months, this sting operation ended up in a Bank of America vault where the moon rock was seized. The Moon rock was then subject to a 5 year civil case known as: "United States of America v. One Lucite Ball containing Lunar Material (one Moon Rock) and One Ten Inch by Fourteen Inch Wooden Plaque", which resulted in the forfeiture of the moon rock to the Federal Government on March 24, 2003.

After the Moon rock was officially handed back to the American Government it was sent back to Johnson Space Center where it was made available to once again present to the people of Honduras, which happened on September 22, 2003 in a ceremony at NASA's Headquarters in Washington, D.C. where NASA Administrator Sean O'Keefe presented the moon rock to Ambassador Mario M. Canahuati, of Honduras. Also in attendance at this ceremony was Joseph Gutheinz, who gave a first hand account of how the sting operation transpired to Ambassador Canahuati. Finally on February 28, 2004 NASA administrator Sean O'Keefe flew to Honduras where he formally presented the moon rock to Honduran president Ricardo Maduro. In 2007, Joe Gutheinz was featured in the BBC Two documentary Moon for Sale talking about the Honduras Goodwill Moon Rock, and this unique case. ^{[4] [5] [6] [7] [8]}

[edit] NASA intern theft

In June 2002, 101 grams of moon rocks were stolen from the Johnson Space Center by interns Thad Roberts and Tiffany Fowler. The pair used knowledge of the security around the rocks gained during their internship to remove a 600 pound safe containing the samples.^[9] Roberts is a certified pilot and scuba diver who was an ambitious student pursuing degrees in Physics, Geology and Anthropology who aspired to be an astronaut.^[10] Fellow interns Gordon McWhorter and Shae Saur were also later arrested for their role in the theft and attempted sale of the rocks.^[11] The theft also included a meteorite that may have revealed information about life on Mars. ^[12]

Roberts advertised the rocks to a Belgian mineralogy club website which was forwarded to the FBI who, with the help of Belgian amateur astronomer Axel Emmermann, set up a sting in Orlando, Florida in July 2002 where Roberts and Fowler were arrested.^[11] Roberts was also charged with stealing Dinosaur bones and other fossils from his school, the University of Utah.^[13][14]

[edit] See also

Wikimedia Commons has media related to: Lunar samples

• Geology of the Moon
• Lunar Receiving Laboratory
• Lunar meteorite
• Lunar ice
• Lunar soil
• Helium-3

[edit] References

• Louis Varricchio,Inconstant Moon, Xlibris Books, 2006, ISBN 1-59926-393-9.

[edit] External links

• Rocks & Soils from the Moon — Johnson Space Center
• Apollo Geology Tool Catalog
• Lunar meteorites — Washington University, Department of Earth and Planetary Sciences
• Lunar Samples Lunar and Planetary Institute
• Articles about Moon rocks in Planetary Science Research Discoveries educational journal

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