| phd
| |
| Claude de l’Aubespine, seigneur d’Hauterive | 1 April 1547 | 1567 |
| Jacques Bourdin, seigneur de Villeines | 1558 | 1567 |
| Florimond II Robertet, seigneur de Fresnes | 1558 | 1567 |
| Claude de l’Aubespine, comte d’Hauterive | 8 July 1567 | September 1570 |
| Florimond III Robertet d’Alluye | 1567 | 1569 |
| Simon Fizes, baron de Sauves | 22 October 1567 | 1579 |
| Nicolas de Neufville, seigneur de Villeroy | 28 October 1567 | 1588 |
| Pierre Bruslart, seigneur de Genlis | 8 June 1569 | 1588 |
| Louis de Revol | 1 January 1589 | 17 September 1594 |
| Nicolas de Neufville, seigneur de Villeroy | 30 December 1594 | 9 August 1616 |
| Armand Jean du Plessis, duc de Richelieu, Bishop of Luçon | 30 November 1616 | 24 April 1617 |
| Pierre Brulart, vicomte de Puysieux | 24 April 1617 | 11 March 1626 |
| Raymond Phelypeaux, seigneur d'Herbault | 11 March 1626 | 2 May 1629 |
| Claude Bouthillier | 2 May 1629 | 18 March 1632 |
| Léon Bouthillier, comte de Chavigny | 18 March 1632 | 23 June 1643 |
| Henri-Auguste de Loménie, comte de Brienne | 23 June 1643 | 3 April 1663 |
| Hugues de Lionne | 3 April 1663 | 1 September 1671 |
| Simon Arnauld, marquis de Pomponne | 1 September 1671 | 18 November 1679 |
| Charles Colbert, marquis de Croissy | 12 February 1680 | 28 July 1696 |
| Jean-Baptiste Colbert, marquis de Torcy | 28 July 1696 | 22 September 1715 |
| Nicolas du Blé, marquis d'Huxelles | 23 September 1715 | 1 September 1718 |
| Guillaume Dubois | 24 September 1718 | 10 August 1723 |
| Charles Jean-Baptiste Fleuriau, comte de Morville | 16 August 1723 | 19 August 1727 |
| Germain Louis Chauvelin | 23 August 1727 | 20 February 1737 |
| Jean-Jacques Amelot de Chaillou | 22 February 1737 | 26 April 1744 |
| Adrien Maurice, duc de Noailles | 26 April 1744 | 19 November 1744 |
| René de Voyer de Paulmy, marquis d'Argenson | 19 November 1744 | 10 January 1747 |
| Louis Philogène Brûlart, vicomte de Puisieulx | 27 January 1747 | 9 September 1751 |
| François Dominique de Barberie de Saint-Contest | 11 September 1751 | 24 July 1754 |
| Antoine Louis Rouillé | 24 July 1754 | 28 June 1757 |
| François Joachim de Pierre de Bernis | 28 June 1757 | 9 October 1758 |
| Étienne François, duc de Choiseul | 3 December 1758 | 13 October 1761 |
| César Gabriel de Choiseul-Chevigny, duc de Praslin | 13 October 1761 | 10 April 1766 |
| Étienne François, duc de Choiseul | 10 April 1766 | 24 December 1770 |
| Louis Phélypeaux, duc de La Vrillère | 24 December 1770 | 6 June 1771 |
| Emmanuel Armand de Vignerot du Plessis de Richelieu, duc d'Aiguillon | 6 June 1771 | 2 June 1774 |
| Henri Léonard Jean Baptiste Bertin | 2 June 1774 | 21 July 1774 |
| Charles Gravier, comte de Vergennes | 21 July 1774 | 13 February 1787 |
| Armand Marc, comte de Montmorin Saint-Hérem | 14 February 1787 | 13 July 1789 |
| Paul François de Quelen, duc de la Vauguyon | 13 July 1789 | 16 July 1789 |
| Armand Marc, comte de Montmorin Saint-Hérem | 16 July 1789 | 29 November 1791 |
| Claude Antoine Valdec de Lessart | 29 November 1791 | 15 March 1792 |
| Charles Dumouriez | 15 March 1792 | 13 June 1792 |
| Pierre Paul de Méredieu, baron de Naillac | 13 June 1792 | 18 June 1792 |
| Scipion Victor, marquis de Chambonas | 18 June 1792 | 23 July 1792 |
| François Joseph de Gratet, vicomte Dubouchage | 23 July 1792 | 1 August 1792 |
| Claude Bigot de Sainte-Croix | 1 August 1792 | 10 August 1792 |
| Pierre Henri Hélène Marie Lebrun-Tondu | 10 August 1792 | 21 June 1793 |
| François Louis Michel Chemin Deforgues | 21 June 1793 | 2 April 1794 |
| Jean Marie Claude Alexandre Goujon | 5 April 1794 | 8 April 1794 |
| Martial Joseph Armand Herman | 8 April 1794 | 20 April 1794 |
| none | 20 April 1794 | 3 November 1795 |
| Charles Delacroix | 3 November 1795 | 15 July 1797 |
| Charles Maurice de Talleyrand-Périgord | 15 July 1797 | 20 July 1799 |
| Karl Reinhard | 20 July 1799 | 22 November 1799 |
| Charles Maurice de Talleyrand, prince de Bénévent | 22 November 1799 | 9 August 1807 |
| Jean-Baptiste Nompère de Champagny, duc de Cadore | 9 August 1807 | 17 April 1811 |
| Hugues Bernard Maret, duc de Bassano | 17 April 1811 | 20 November 1813 |
| Armand Augustin Louis Caulaincourt, duc de Vicence | 20 November 1813 | 1 April 1814 |
| Antoine René Charles Mathurin, comte de Laforest | 3 April 1814 | 13 May 1814 |
| Charles Maurice de Talleyrand-Périgord, prince de Bénévent | 13 May 1814 | 20 March 1815 |
| Armand Augustin Louis Caulaincourt, duc de Vicence | 20 March 1815 | 22 June 1815 |
| Louis, baron Bignon | 22 June 1815 | 7 July, 1815 |
| Charles Maurice de Talleyrand-Périgord, prince de Bénévent | 9 July 1815 | 26 September 1815 |
| Armand Emmanuel du Plessis, duc de Richelieu | 26 September 1815 | 29 December 1818 |
| Jean Joseph Paul Augustin, marquis Dessolles | 29 December 1818 | 19 November 1819 |
| Étienne Denis, baron Pasquier | 19 November 1819 | 14 December 1821 |
| Mathieu Jean Félicité, duc de Montmorency-Laval | 14 December 1821 | 28 December 1822 |
| François-René, vicomte de Chateaubriand | 28 December 1822 | 4 August 1824 |
| Ange Hyacinthe Maxence, baron de Damas | 4 August 1824 | 4 January 1828 |
| Auguste, comte de La Ferronays | 4 January 1828 | 24 April 1829 |
| Anne Pierre Adrien, duc de Montmorency-Laval | 24 April 1829 | 14 May 1829 |
| Joseph-Marie, comte Portalis | 14 May 1829 | 8 August 1829 |
| Jules Armand Auguste Marie, prince de Polignac | 8 August 1829 | 29 July 1830 |
| Victor Louis Victurnien, duc de Mortemart | 29 July 1830 | 29 July 1830 |
| Louis, baron Bignon | 31 July 1830 | 1 August 1830 |
| Jean-Baptiste, comte Jourdan | 1 August 1830 | 11 August 1830 |
| Louis, comte Molé | 11 August 1830 | 2 November 1830 |
| Nicolas Joseph, marquis Maison | 2 November 1830 | 17 November 1830 |
| Horace François Bastien, baron Sébastiani | 17 November 1830 | 11 October 1832 |
| Victor, duc de Broglie | 11 October 1832 | 4 April 1834 |
| Henri Gauthier, comte de Rigny | 4 April 1834 | 10 November 1834 |
| Charles Joseph, comte Bresson | 10 November 1834 | 18 November 1834 |
| Henri Gauthier, comte de Rigny | 18 November 1834 | 12 March 1835 |
| Victor, duc de Broglie | 12 March 1835 | 22 February 1836 |
| Adolphe Thiers | 22 February 1836 | 6 September 1836 |
| Louis, comte Molé | 6 September 1836 | 31 March 1839 |
| Napoléon Auguste Lannes, duc de Montebello | 31 March 1839 | 12 May 1839 |
| Nicolas Jean de Dieu Soult, duc de Dalmatie | 12 May 1839 | 1 March 1840 |
| Adolphe Thiers | 1 March 1840 | 29 October 1840 |
| François Guizot | 29 October 1840 | 23 February 1848 |
| Alphonse de Lamartine | 24 February 1848 | 11 May 1848 |
| Jules Bastide | 11 May 1848 | 29 June 1848 |
| Marie-Alphonse Bedeau | 29 June 1848 | 17 July 1848 |
| Jules Bastide | 17 July 1848 | 20 December 1848 |
| Édouard Drouyn de Lhuys | 20 December 1848 | 2 June 1849 |
| Alexis de Tocqueville | 2 June 1849 | 31 October 1849 |
| Alphonse de Rayneval | 31 October 1849 | 17 November 1849 |
| Jean-Ernest Ducos, vicomte de La Hitte | 17 November 1849 | 9 January 1851 |
| Édouard Drouyn de Lhuys | 9 January 1851 | 24 January 1851 |
| Anatole, baron Brénier de Renaudière | 24 January 1851 | 10 April 1851 |
| Jules Baroche | 10 April 1851 | 26 October 1851 |
| Louis Félix Étienne, marquis de Turgot | 26 October 1851 | 28 July 1852 |
| Édouard Drouyn de Lhuys | 28 July 1852 | 7 May 1855 |
| Alexandre Colonna, comte Walewski | 7 May 1855 | 4 January 1860 |
| Jules Baroche | 4 January 1860 | 24 January 1860 |
| Édouard Thouvenel | 24 January 1860 | 15 October 1862 |
| Édouard Drouyn de Lhuys | 15 October 1862 | 1 September 1866 |
| Charles, marquis de La Valette | 1 September 1866 | 2 October 1866 |
| Lionel, marquis de Moustier | 2 October 1866 | 17 December 1868 |
| Charles, marquis de La Valette | 17 December 1868 | 17 July 1869 |
| Henri, prince de La Tour d'Auvergne | 17 July 1869 | 2 January 1870 |
| Napoléon, comte Daru | 2 January 1870 | 14 April 1870 |
| Émile Ollivier | 14 April 1870 | 15 May 1870 |
| Agenor, duc de Gramont | 15 May 1870 | 10 August 1870 |
| Henri, prince de La Tour d'Auvergne | 10 August 1870 | 4 September 1870 |
| Jules Favre | 4 September 1870 | 2 August 1871 |
| Charles, comte de Rémusat | 2 August 1871 | 25 May 1873 |
| Albert, duc de Broglie | 25 May 1873 | 26 November 1873 |
| Louis Decazes, duc de Glucksberg | 29 November 1873 | 23 November 1877 |
| Gaston-Robert, marquis de Banneville | 23 November 1877 | 13 December 1877 |
| William Henry Waddington | 13 December 1877 | 28 December 1879 |
| Charles de Freycinet | 28 December 1879 | 23 September 1880 |
| Jules Barthélemy-Saint-Hilaire | 23 September 1880 | 14 November 1881 |
| Léon Gambetta | 14 November 1881 | 30 January 1882 |
| Charles de Freycinet | 30 January 1882 | 7 August 1882 |
| Charles Duclerc | 7 August 1882 | 29 January 1883 |
| Armand Fallières | 29 January 1883 | 21 February 1883 |
| Paul-Armand Challemel-Lacour | 21 February 1883 | 20 November 1883 |
| Jules Ferry | 20 November 1883 | 6 April 1885 |
| Charles de Freycinet | 6 April 1885 | 11 December 1886 |
| Émile Flourens | 11 December 1886 | 3 April 1888 |
| René Goblet | 3 April 1888 | 22 February 1889 |
| Eugène Spuller | 22 February 1889 | 17 March 1890 |
| Alexandre Ribot | 17 March 1890 | 11 January 1893 |
| Jules Develle | 11 January 1893 | 3 December 1893 |
| Jean Casimir-Perier | 3 December 1893 | 30 May 1894 |
| Gabriel Hanotaux | 30 May 1894 | 1 November 1895 |
| Marcellin Berthelot | 1 November 1895 | 28 March 1896 |
| Léon Bourgeois | 28 March 1896 | 29 April 1896 |
| Gabriel Hanotaux | 29 April 1896 | 28 June 1898 |
| Théophile Delcassé | 28 June 1898 | 6 June 1905 |
| Maurice Rouvier | 6 June 1905 | 13 March 1906 |
| Léon Bourgeois | 14 March 1906 | 25 October 1906 |
| Stéphen Pichon | 25 October 1906 | 2 March 1911 |
| Jean Cruppi | 2 March 1911 | 27 June 1911 |
| Justin de Selves | 27 June 1911 | 9 January 1912 |
| Raymond Poincaré | 14 January 1912 | 22 January 1913 |
| Charles Jonnart | 22 January 1913 | 22 March 1913 |
| Stéphen Pichon | 22 March 1913 | 9 December 1913 |
| Gaston Doumergue | 9 December 1913 | 9 June 1914 |
| Léon Bourgeois | 9 June 1914 | 13 June 1914 |
| René Viviani | 13 June 1914 | 3 August 1914 |
| Gaston Doumergue | 3 August 1914 | 26 August 1914 |
| Théophile Delcassé | 26 August 1914 | 13 October 1915 |
| René Viviani | 13 October 1915 | 29 October 1915 |
| Aristide Briand | 29 October 1915 | 20 March 1917 |
| Alexandre Ribot | 20 March 1917 | 23 October 1917 |
| Louis Barthou | 23 October 1917 | 16 November 1917 |
| Stéphen Pichon | 16 November 1917 | 20 January 1920 |
| Alexandre Millerand | 20 January 1920 | 24 September 1920 |
| Georges Leygues | 24 September 1920 | 16 January 1921 |
| Aristide Briand | 16 January 1921 | 15 January 1922 |
| Raymond Poincaré | 15 January 1922 | 9 June 1924 |
| Edmond Lefebvre du Prey | 9 June 1924 | 14 June 1924 |
| Édouard Herriot | 14 June 1924 | 17 April 1925 |
| Aristide Briand | 17 April 1925 | 19 July 1926 |
| Édouard Herriot | 19 July 1926 | 23 July 1926 |
| Aristide Briand | 23 July 1926 | 14 January 1932 |
| Pierre Laval | 14 January 1932 | 20 February 1932 |
| André Tardieu | 20 February 1932 | 3 June 1932 |
| Édouard Herriot | 3 June 1932 | 18 December 1932 |
| Joseph Paul-Boncour | 18 December 1932 | 30 January 1934 |
| Édouard Daladier | 30 January 1934 | 9 February 1934 |
| Louis Barthou | 9 February 1934 | 9 October 1934 |
| Pierre Laval | 13 October 1934 | 24 January 1936 |
| Pierre Étienne Flandin | 24 January 1936 | 4 June 1936 |
| Yvon Delbos | 4 June 1936 | 13 March 1938 |
| Joseph Paul-Boncour | 13 March 1938 | 10 April 1938 |
| Georges Bonnet | 10 April 1938 | 13 September 1939 |
| Édouard Daladier | 13 September 1939 | 21 March 1940 |
| Paul Reynaud | 21 March 1940 | 18 May 1940 |
| Édouard Daladier | 18 May 1940 | 5 June 1940 |
| Paul Reynaud | 5 June 1940 | 16 June 1940 |
| Paul Baudoin | 16 June 1940 | 28 October 1940 |
| Pierre Laval | 28 October 1940 | 13 December 1940 |
| Pierre Étienne Flandin | 13 December 1940 | 9 February 1941 |
| François Darlan | 10 February 1941 | 18 April 1942 |
| Pierre Laval | 18 April 1942 | 20 August 1944 |
| Free French Commissioners |
| Maurice Dejean | 24 September 1941 | 17 October 1942 |
| René Pleven | 17 October 1942 | 5 February 1943 |
| René Massigli | 5 February 1943 | 10 September 1944 |
| Ministers |
| Georges Bidault | 10 September 1944 | 16 December 1946 |
| Léon Blum | 16 December 1946 | 22 January 1947 |
| Georges Bidault | 22 January 1947 | 26 July 1948 |
| Robert Schuman | 26 July 1948 | 8 January 1953 |
| Georges Bidault | 8 January 1953 | 19 June 1954 |
| Pierre Mendès-France | 19 June 1954 | 20 January 1955 |
| Edgar Faure | 20 January 1955 | 23 February 1955 |
| Antoine Pinay | 23 February 1955 | 1 February 1956 |
| Christian Pineau | 1 February 1956 | 14 May 1958 |
| René Pleven | 14 May 1958 | 1 June 1958 |
| Maurice Couve de Murville | 1 June 1958 | 30 May 1968 |
| Michel Debré | 30 May 1968 | 22 June 1969 |
| Maurice Schumann | 22 June 1969 | 15 March 1973 |
| André Bettencourt | 15 March 1973 | 4 April 1973 |
| Michel Jobert | 4 April 1973 | 28 May 1974 |
| Jean Sauvagnargues | 28 May 1974 | 27 August 1976 |
| Louis de Guiringaud | 27 August 1976 | 29 November 1978 |
| Jean François-Poncet | 29 November 1978 | 22 May 1981 |
| Claude Cheysson | 22 May 1981 | 7 December 1984 |
| Roland Dumas | 7 December 1984 | 20 March 1986 |
| Jean-Bernard Raimond | 20 March 1986 | 12 May 1988 |
| Roland Dumas | 12 May 1988 | 29 March 1993 |
| Alain Juppé | 29 March 1993 | 18 May 1995 |
| Hervé de Charette | 18 May 1995 | 4 June 1997 |
| Hubert Védrine | 4 June 1997 | 7 May 2002 |
| Dominique de Villepin | 7 May 2002 | 31 March 2004 |
| Michel Barnier | 31 March 2004 | 2 June 2005 |
| Philippe Douste-Blazy | 2 June 2005 | 15 May 2007 |
| Bernard Kouchner | 16 May 2007 |
