A closed system is a system in the "state of being isolated from its surrounding environment."^[1] The term often refers to an idealized system in which closure is perfect. In reality no system can be completely closed; there are only varying degrees of closure.

In thermodynamics, a closed system can exchange heat and work (aka energy), but not matter, with its surroundings. In contrast an isolated system can not exchange any of heat, work, or matter with the surroundings, while an open system can exchange all of heat, work and matter. For a simple system, with only one type of particle (atom or molecule), a closed system amounts to a constant number of particles. However, for systems which are undergoing a chemical reaction, there may be all sorts of molecules being generated and destroyed by the reaction process. In this case, the fact that the system is closed is expressed by saying that the total number of each elemental atom is conserved, no matter what kind of molecule it may be a part of. Mathematically:

where N_j is the number of j-type molecules, a_ij is the number of atoms of element i in molecule j and b_i⁰ is the total number of atoms of element i in the system, which remains constant, since the system is closed. There will be one such equation for each different element in the system.

[edit] See also

• Glossary of systems theory
• Dynamical system
• Isolated system
• Open system (systems theory)
• Thermodynamic system

[edit] References

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