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Chromite
General
Category Mineral
Chemical formula iron magnesium chromium oxide: (Fe, Mg)Cr2O4
Identification
Color Black to brownish black
Crystal habit Octahedral rare; massive to granular
Crystal system Isometric; hexoctahedral
Cleavage absent
Fracture Conchoidal
Mohs scale hardness 5.5
Luster Submetallic
Streak Dark brown
Specific gravity 4.5 - 4.8
Refractive index Subtranslucent to opaque
Fusibility Infusible
Other characteristics Weakly magnetic
Major varieties

Chromite is iron magnesium chromium oxide: (Fe, Mg)Cr2O4. It is an oxide mineral belonging to the spinel group. Magnesium can substitute for iron in variable amounts; also, aluminium and ferric iron commonly substitute for chromium.

Contents

[edit] Occurrence

Chromite is found in peridotite from the Earth's mantle. It also occurs in layered ultramafic intrusive rocks.[1] In addition, it is found in metamorphic rocks such as some serpentinites. Ore deposits of chromite form as early magmatic differentiates. It is commonly associated with olivine, magnetite, serpentine, and corundum. The vast Bushveld igneous complex of South Africa is a large layered mafic to ultramafic igneous body with some layers consisting of 90% chromite making the rare rock type, chromitite.

[edit] Uses

Chromite from Albania

Chromite is also used as a refractory material, because it has a high heat stability.[2]

The only ore of chromium is the mineral chromite. The two main products of chromite refining are ferrochromium and metallic chromium, for those products the ore smelter process differs considerably. For the production of ferrochromium the chromite ore (FeCr2O4) is reduced with either aluminium or silicon in a aluminothermic reaction and for the production of pure chromium the iron has to be separated from the chromium in a two step roasting and leaching process.[3]

[edit] Mining

Chromium ore output in 2002

In 2002 14,600,000 metric tons of chromite have been mined. The largest producers have been South Africa (44%) India (18%), Kazakhstan (16%) Zimbabwe (5%), Finland (4%) Iran (4%) and Brazil (2%) with several other countries producing the rest of less than 10% of the world production. [4][5]

[edit] Minor production

In Pakistan, Chromite is mined from the ultramafic rocks in mainly the Muslim Bagh area of Zhob District of Balochistan. Most of the chromite is of metallurgical grade with Cr2O3 averaging 40% and a chrome to iron ratio of 2.6:1. Afghanistan has significant deposits of high grade Chromite ore.

Recently, the biggest user of Chromite ore has been China, importing large quantities from South Africa, Pakistan and other countries. The concentrate is used to make ferrochromium, which is in turn used to make stainless steel and some others alloys.

[edit] References

  1. ^ Gu, F (1988). "Chromite- mineralogy and processing". Minerals Engineering 1: 235. doi:10.1016/0892-6875(88)90045-3. 
  2. ^ Routschka, Gerald (2008). Pocket Manual Refractory Materials: Structure - Properties - Verification. Vulkan-Verlag. ISBN 9783802731587. http://books.google.de/books?id=0ugkNtlWKWEC&pg=PA205. 
  3. ^ Papp, John F.; Lipin Bruce R. (2006). "Chromite". Industrial Minerals & Rocks: Commodities, Markets, and Uses (7th ed.). SME. ISBN 9780873352338. http://books.google.de/books?id=zNicdkuulE4C&pg=PA309. 
  4. ^ Papp, John F.. "Mineral Commodity Summary 2006: Chromium". United States Geological Survey. http://minerals.usgs.gov/minerals/pubs/commodity/chromium/chrommcs06.pdf. Retrieved 2009-02-24. 
  5. ^ Papp, John F.. "Minerals Yearbook 2006: Chromium". United States Geological Survey. http://minerals.usgs.gov/minerals/pubs/commodity/chromium/myb1-2006-chrom.pdf. Retrieved 2009-02-24. 

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