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Baddeleyite

Baddeleyite in corundum gneiss
General
Category Oxide mineral
Chemical formula ZrO2
Strunz classification 04.DE.35
Dana classification 04.04.14.01
Identification
Color Colorless to yellow, green, greenish or reddish brown, brown, iron-black
Crystal habit Tabular prismatic, radially fibrous in botryoidal masses
Crystal system Monoclinic - prismatic
Twinning Ubiquitous polysynthetic on {100} and {110}
Cleavage {001} Distinct
Fracture Irregular uneven to subconchoidal
Tenacity Brittle
Mohs scale hardness 6.5
Luster Greasy to vitreous
Streak White
Diaphaneity Transparent to translucent
Specific gravity 5.5 - 6
Optical properties Biaxial (-)
Refractive index nα = 2.130 nβ = 2.190 nγ = 2.200
Birefringence δ = 0.070
Pleochroism X = yellow, reddish brown, oil-green; Y = oil-green, reddish brown; Z = brown, light brown
Other characteristics Blue-green cathodoluminescence
References [1][2][3]

Baddeleyite is a rare zirconium oxide mineral (ZrO2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction (nα = 2.130, nβ = 2.190, and nγ = 2.200), and ranges from colorless to yellow, green, and dark brown. The mineral has a specific gravity of 5.5 to 6 and a Mohs hardness of 6.5. Baddeleyite is a refractory mineral, with a melting point of 2 700 °C. Hafnium is a substituting impurity and may be present in quantities ranging from 0.1 to several percents.

Baddeleyite was first described in 1892 from Sri Lanka, and Minas Gerais and Jacupiranga, São Paulo, Brazil. It was named after Joseph Baddeley, who described the occurrences in Sri Lanka.[1]

Baddeleyete is often found as detrital grains in gravels. Its primary occurrence is in high temperature veins and in syenite, carbonatite, kimberlite, and lamproite intrusions. Because of their refractory nature and stability under diverse conditions, baddeleyete grains, along with zircon, are used for uranium-lead radiometric age determinations.

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