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4-Hydroxybenzoic acid
4-Hydroxybenzoic acid
IUPAC name
Other names p-Hydroxybenzoic acid
para-Hydroxybenzoic acid
Identifiers
CAS number 99-96-7 Yes check.svgY
PubChem 135
SMILES
Properties
Molecular formula C7H6O3
Molar mass 138.12074 g/mol
Density 1.46 g/cm³
Melting point

214-217 °C

 Yes check.svgY (what is this?)  (verify)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

4-Hydroxybenzoic acid, or p-hydroxybenzoic acid, is a phenolic derivative of benzoic acid. It is a white crystalline solid that is slightly soluble in water and chloroform, but soluble to extremely soluble in alcohols, ether, and acetone.

4-Hydroxybenzoic acid is primarily known as the basis for the preparation of its esters, known as parabens, which are used as preservatives in cosmetics.

[edit] Production

4-Hydroxybenzoic acid is produced commercially from potassium phenoxide and carbon dioxide in the Kolbe-Schmitt reaction.[citation needed] It can also be produced in the laboratory by heating potassium salicylate with potassium carbonate to 240 °C, followed by treating with acid.[1]

[edit] See also

The closely related 2-hydroxybenzoic acid is known as salicylic acid, a precursor to aspirin.

[edit] References

  1. ^ C. A. Buehler and W. E. Cate (1943), "p-Hydroxybenzoic acid", Org. Synth., http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=CV2P0341 ; Coll. Vol. 2: 341 



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